Make Acetone Peroxide: A Primary High Explosive
Written By
ChristopherVoute
Published 4 months ago
Last edited 4 months ago

Acetone peroxide is a primary high explosive. It is the product of the reaction between hydrogen peroxide and acetone and is an acid catalyst. It is notable for being a high explosive that does not contain nitrogen, but is very unstable and typically too dangerous for practical uses in an impure form. The oxidization that occurs when burning is: 

2 C9H18O6 + 21 O2 ? 18 H2O + 18 CO2

These are some photos of the exothermic reaction:

How To Make Acetone Peroxide: A Primary High Explosive

For more information on acetone peroxide and its dangers and characteristics, click here.

Step 1 Materials

  • 50 ml acetone (purchase at your local hardware store)
  • 25 ml of 30% hydrogen peroxide (can be found at K-Mart, Safeway, a hair salon, pharmacies, and many other places. I find the best concentration is sold as a hair bleaching product)
  • 5 ml muriatic acid (also known as hydrochloric acid, it can be found at most hardware stores)

How To Make Acetone Peroxide: A Primary High Explosive

Step 2 Procedure

  1. Pour the H2O2 (hydrogen peroxide) into a glass jar. 
  2. Add the acetone to the glass jar.
  3. Slowly add the HCl (muriatic/hydrochloric acid) into the glass jar.
  4. Keep in a refrigerator for one day.  This is very important! If made above 10 degrees celsius, the reaction will produce the "dimmer" of the two possible molecular variations. This is much too dangerous for use! By lowering the temperature of the reaction below 10 degrees, you are creating the trimmer, a more stable form of acetone peroxide. See here for more information.
  5. Filter the liquid, then let dry. 

Once dry, you should see fine, white crystals. Scrape carefully (VERY carefully! Acetone peroxide can be ignited by touch!) into a container with a perforated lid, but do not store for more than a week! Acetone peroxide has been known to spontaneously explode.

Final Product

The video below is the final result, which shows 0.5 grams of acetone peroxide detonated in a metal container emerged in water. I used an electric ignition method, but a long fuse would work just as well.

Tips

  • Use an incandecent light bulb to speed the drying process, but do not leave unattended! 
  • Once dry, test your final product by lighting a tiny amount on a probe. The result should be a large fireball: Be careful! Its unexpected. 
  • Try and find the highest concentration of Hydrogen Peroxide possible. The higher the concentration, the better the result!

Warnings

  • This is for demonstration purposes only: DO NOT TRY THIS AT HOME!
  • I am not responsible for any damage or harm you cause!
  • This is a high explosive! Explosives are dangerous and illegal in many countries. 

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Comments

+2
Ben (13) 1/11/12 9:58 AM
If you use an incandescent bulb to dry this it doesn't matter if you leave it unattended or not, if it is initiated there's nothing you will be able to do about it. Several people have died doing just that. Anyone who knows enough about explosives to safely use them would never use acetone peroxide. It is far too unstable for any safe use. You may use it repeatedly with no incident and believe you are safe, but without a doubt it will bite you in due time.
+2
Ben (13) 1/11/12 10:05 AM
Further, you mention to 'scrape' the peroxide, not mentioning how incredibly sensitive it is to friction. There is also no mention of the variations to the molecule (diacetone vs triacetone) that are even more dangerous and are likely to result from just the slightest mistake in the introduction of the acid or the wrong reaction temperature. This is just enough information to get someone hurt. Please delete it.
-2
zZz (-5) 5/4/12 10:28 PM
Ok master Ben he will delete it You friggin nard, Freedom of speech freedom of expression, gee Ben You think You might be that one to try it? maybe give us all a breather from Your admin type attitudes... Japha if you dont know what japha is then if You do You know Your just a power hungry administrator lol go away ben, But in all seriousness the next article is goign to be how to commit suicide the proper way 'thus' succeding at it Your very first try... Later Days....
+2
Ben (13) 5/5/12 12:26 PM
You are foolish if you think what I said violates of freedom of speech. Having the right to say whatever you please does not mean that all words are free of consequence. By your very own logic you yourself are in the wrong for denying my right to say whatever I please in previous comments. Further, regarding this article, you would be wise to listen to my previous warnings. They come from one who has made fireworks from the ground up for competition for more than a decade, and holds a federal explosives manufacturing license.
+2
ChristopherVoute (56) 5/5/12 12:39 PM
I gotta agree with Ben on that one, his warnings are accurate and well placed, Acetone Peroxide is very dangerous. I wrote this article for informational purposes only, because I found it fascinating how such simplistic, easy to purchase chemicals could form such a viscous explosive. We appreciate your input zZz, however, please word your comments in a less belligerent way in the future.
+3
ChristopherVoute (56) 1/11/12 10:38 AM
I agree, acetone peroxide is an extremely dangerous explosive. First, by refrigerating the initial reaction between the acetone and the hydrogen peroxide, you are creating the "trimmer" which is the second molecule variation you mentioned. This is relatively safe to handle, and will not go off at the touch. Second, this article is for informational and demonstration purposes only. NOT to be attempted. Thirdly, the reaction between the specified amount of ingredients will only make a small amount of acetone peroxide, not enough to cause serious damage in the process. However, when placed in a confined space, it is extremely dangerous.
+2
ChristopherVoute (56) 1/11/12 10:48 AM
Regardless, thank you for the tip, i have added in the information about molecular variations, and also provided more warnings of the volatility of acetone peroxide.
+1
Scrumps (30) 1/11/12 11:30 AM
Yea so - I'm all for sharing information, but this seems like its going to get me added to some watch list for something.

People are obviously going to see the listed ingredients, and seeing as there are steps and advice on how to make it, I don't think you can really claim its for "demonstration" only.

Seems very dangerous...
+2
Stefan Bugovsky (1) 1/12/12 4:48 AM
There are much less dangerous experiments that involve fire by exothermic reaction that don't involve bodily harm. Try Potassium permanganate and (if possible) water free glycerine. It will react a minute later with a small sizzle and a flame and won't explode. For special effects you can also mix the permanganate with hydrogen peroxide. It will result in a boiling geyser with lots of vapour. Stay away from mixing hydrogen peroxide with so highly inflammable stuff as acetone. All the chemists around me (myself included) would stay away from high explosives for good reason. There's a joke amongst us: How do you recognise a chemist dabbling with high explosives in his garage? You can't shake hands with him.
+1
ChristopherVoute (56) 1/12/12 8:09 AM
haha, nice. yes, high explosives are dangerous. still, the concept is important to chemistry, without it we would not have combustion engine or firearms, and any number of things we take for granted.
+1
plack 1/24/12 8:26 PM
About four years ago I experimented with AP and the way it responds under different circumstances. When igniting small "pea size" amount (on 1/2 in thick sheet of plywood) I got small plume of fire. "Dime size" amount, even larger plume.
When I got up to 3 grams or "quarter" size amount it imploded making a large Bang that rang my ears for about ten min and put a hole through the plywood... Just a thought to all you people who think it's cool to ignite it in your hand...
+1
plack 1/24/12 8:54 PM
For the record, I used food grade H2O2 and concentrated H2SO4 as the catalyst ..and needless to say I don't mess with the stuff anymore.. And although I hate that the info is available I'll fight to the death for your right to post it.
+1
Joseph Serrano 2/1/12 7:36 PM
could this be used for some type of squib for movies perhaps?
+1
ChristopherVoute (56) 2/1/12 9:55 PM
not sure what you mean by "squib"?
+1
freddy furbelow (2) 2/5/12 5:48 AM
"Squib" is used in display pyrotechnics.
+1
ChristopherVoute (56) 2/5/12 7:20 AM
ah! well, i suppose it could work, but it wouldnt be the best choice. something like flashpowder or similar oxidiser-metal-sensitizer would work better :)
+1
freddy furbelow (2) 2/5/12 11:55 AM
Not saying that I would use it. In mining a squib is also referred to as a "slow match", which definitely takes acetone peroxide out of the picture. I used to experiment with the picrates until a shock-sensitive compound exploded prematurely.
+2
JT Newsome (12) 2/24/12 3:29 AM
We blow things up that are more explosive than this in my University's chemistry lab all the time! The author gave clear instructions and described precisely what was being made in simple scientific terms. I think you could learn a lot from this and support it remaining on this site. Knowledge is power and power can be used for good or for bad, it's all in the person. Someone could indeed get hurt from this, but you risk dying in a car accident every day. It should be up to the person what sorts of risks they want or do not want to take. That is my opinion anyhow...Great article, I look forward to future posts.
+1
ChristopherVoute (56) 2/24/12 8:05 AM
Thank you! :) Ive always loved chemistry, i never get tired of how amazing it is to take two ordinary, boring substances and turn them into something furiously powerful.
+1
leeman66 3/9/12 7:47 AM
So if anybody even reads this. are they considered a Terrorist or are they just someone surfin the net 4 survival? I mean I saved my lunch money ,I think for my 1st chemistry set,thx 2 mum. :(
+1
JT Newsome (12) 3/9/12 10:27 AM
You're only a terrorist if you use your knowledge to blow people up otherwise you are just a crazy scientist who likes to learn and watch super-awesome chemical reactions!? :)
+1
zZz (-5) 5/4/12 10:34 PM
and there you have it, someone with a sense of humor instead of a worry wart, hey if some insane dewderz is going to mix this concoction up and kill the masses it will be on the eleven oclock news let the author of the well explained article be at peace geez already, a grain of salt not an atomic bomb of worry wart juice over us all LOL and so it goes...
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